羊茅麦角碱
| 羊茅麦角碱 | |
|---|---|
| |
| IUPAC名 6,8β-Dimethylergoline | |
| 系统名 (6aR,9R,10aR)-7,9-Dimethyl-4,6,6a,7,8,9,10,10a-octahydroindolo[4,3-fg]quinoline | |
| 别名 | 狐茅麦角碱 |
| 识别 | |
| CAS号 | 569-26-6 
|
| PubChem | 332915 |
| ChemSpider | 294963 |
| SMILES |
|
| 性质 | |
| 化学式 | C16H20N2 |
| 摩尔质量 | 240.34 g·mol−1 |
| 外观 | 白色固体[1] |
| 熔点 | 236—240 °C（509—513 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
羊茅麦角碱（(8β,10β)-6,8-二甲基麦角灵）是一种有机化合物，化学式为C16H20N2，它是一种麥角靈真菌分离物。[2]它可以2-溴-3-硝基苄溴为原料经多步反应、柱分离制得。[1]
参考文献[编辑]
- ^ 1.0 1.1 1.2 Liu, Haichao; Zhang, Xiwu; Shan, Dong; Pitchakuntla, Mallesham; Ma, Yongfan; Jia, Yanxing. Total Syntheses of Festuclavine, Pyroclavine, Costaclavine, epi-Costaclavine, Pibocin A, 9-Deacetoxyfumigaclavine C, Fumigaclavine G, and Dihydrosetoclavine. Organic Letters (American Chemical Society (ACS)). 2017-06-08, 19 (12): 3323–3326. ISSN 1523-7060. doi:10.1021/acs.orglett.7b01504.
- ^ Wallwey, C; Matuschek, M; Xie, XL; Li, SM. Ergot alkaloid biosynthesis in Aspergillus fumigatus: Conversion of chanoclavine-I aldehyde to festuclavine by the festuclavine synthase FgaFS in the presence of the old yellow enzyme FgaOx3. Organic & Biomolecular Chemistry. 2010, 8 (15): 3500–8. PMID 20526482. doi:10.1039/c003823g.