1,6-二苯基己三烯

1,6-二苯基己三烯
	IUPAC名; 1,1′-[(1E,3E,5E)-Hexa-1,3,5-triene-1,6-diyl]dibenzene
别名	(1E,3E,5E)-1,6-Diphenylhexa-1,3,5-triene; [(1E,3E,5E)-6-Phenylhexa-1,3,5-trien-1-yl]benzene; trans,trans,trans-1,6-Diphenylhexatriene; Dicinnamyl
识别
CAS号	1720-32-7 ; 17329-15-6（1E,3E,5E） ; 38557-35-6（1E,3Z,5E） ; 38557-34-5（1E,3E,5Z） ; 170080-16-7（1Z,3E,5Z）
PubChem	5376733
SMILES	C1=CC=C(C=C1)/C=C/C=C/C=C/C2=CC=CC=C2;
EINECS	217-011-3
ChEBI	51594
性质
化学式	C18H16
摩尔质量	232.32 g·mol−1
熔点	199—203 °C（472—476 K）
磁化率	-146.9·10−6 cm3/mol
危险性
	GHS危险性符号;
GHS提示词	警告
H-术语	H315, H319, H335
P-术语	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P332+313, P337+313, P362, P403+233, P405, P501
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1,6-二苯基己三烯或1,6-二苯基己-1,3,5-三烯（DPHT）是一种有机化合物，化学式为C₁₈H₁₆。它可由3,3-二氯-1-丙烯基苯和草酸亚铁的还原偶合反应^[2]，或肉桂醛在吡啶催化下和四氯化钛-锌的偶合反应得到。^[3]它和[Pd₂(CH₃CN)₆][BF₄]₂反应，根据溶剂的不同，可以得到不同配体构型的配合物[Pd₂(DPHT)₂][BF₄]₂。^[4]

参考文献

^ 1,6-Diphenyl-1,3,5-hexatriene at Sigma-Aldrich
^ Jitender M. Khurana, Golak C. Maikap, Sanjay Mehta. Reductive Coupling of Geminal Dichlorides by Iron(II) Oxalate Dihydrate. Synthesis. 1990, 1990 (08): 731–732 [2021-12-13]. ISSN 0039-7881. doi:10.1055/s-1990-26998. （原始内容存档于2018-06-04）（英语）.
^ M.M.V. Ramana, B.K.D. Singh, J.A. Parihar. Microwave-Assisted Coupling of Carbonyl Compound: An Efficient Synthesis of Olefin. Journal of Chemical Research. 2004-11, 2004 (11): 760–761 [2021-12-13]. ISSN 1747-5198. doi:10.3184/0308234043431564. （原始内容存档于2021-12-13）（英语）.
^ Tetsuro Murahashi, Tomoki Nagai, Yukari Mino, Eiko Mochizuki, Yasushi Kai, Hideo Kurosawa. Reversible Interconversion between Dinuclear Sandwich and Half-Sandwich Complexes: Unique Dynamic Behavior of a Pd−Pd Moiety Surrounded by an sp 2 -Carbon Framework. Journal of the American Chemical Society. 2001-07-01, 123 (28): 6927–6928 [2021-12-13]. ISSN 0002-7863. doi:10.1021/ja010027y. （原始内容存档于2021-12-13）（英语）.

[1] 1,6-Diphenyl-1,3,5-hexatriene at Sigma-Aldrich

[2] Jitender M. Khurana, Golak C. Maikap, Sanjay Mehta. Reductive Coupling of Geminal Dichlorides by Iron(II) Oxalate Dihydrate. Synthesis. 1990, 1990 (08): 731–732 [2021-12-13]. ISSN 0039-7881. doi:10.1055/s-1990-26998. （原始内容存档于2018-06-04）（英语）.

[3] M.M.V. Ramana, B.K.D. Singh, J.A. Parihar. Microwave-Assisted Coupling of Carbonyl Compound: An Efficient Synthesis of Olefin. Journal of Chemical Research. 2004-11, 2004 (11): 760–761 [2021-12-13]. ISSN 1747-5198. doi:10.3184/0308234043431564. （原始内容存档于2021-12-13）（英语）.

[4] Tetsuro Murahashi, Tomoki Nagai, Yukari Mino, Eiko Mochizuki, Yasushi Kai, Hideo Kurosawa. Reversible Interconversion between Dinuclear Sandwich and Half-Sandwich Complexes: Unique Dynamic Behavior of a Pd−Pd Moiety Surrounded by an sp 2 -Carbon Framework. Journal of the American Chemical Society. 2001-07-01, 123 (28): 6927–6928 [2021-12-13]. ISSN 0002-7863. doi:10.1021/ja010027y. （原始内容存档于2021-12-13）（英语）.

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