氟溴碘甲烷

氟溴碘甲烷是一種有機化合物，化學式為CHBrFI，具有手性^[2]。它可由氟溴乙酸銀在180~260 °C和碘在真空中反應製得，或由溴二碘甲烷和氟化汞在60 °C反應得到。^[1]

{\ce {CHBrI2 + HgF2 -> CHBrFI + HgI2}}

乙基碘化鋅和二氟碘甲烷反應，可以得到二氟甲基碘化鋅，它存在與氟碘甲基氟化鋅的互變異構，與溴反應，也能得到氟溴碘甲烷。^[3]

參考文獻[編輯]

^ ^1.0 ^1.1 Dong Bo Li, Siu-Choon Ng, Igor Novak. Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI. Tetrahedron. 2002-07, 58 (29): 5923–5926 [2021-11-02]. doi:10.1016/S0040-4020(02)00532-X （英語）.
^ Igor Novak, Dong Bo Li, Anthony W. Potts. Electronic Structure of Chiral Halomethanes. The Journal of Physical Chemistry A. 2002-01-01, 106 (3): 465–468 [2021-11-02]. ISSN 1089-5639. doi:10.1021/jp0116959. （原始內容存檔於2021-10-27）（英語）.
^ Beaulieu, Louis-Philippe B.; Schneider, Jakob F.; Charette, André B. Highly Enantioselective Simmons–Smith Fluorocyclopropanation of Allylic Alcohols via the Halogen Scrambling Strategy of Zinc Carbenoids. Journal of the American Chemical Society (American Chemical Society (ACS)). 2013-05-20, 135 (21): 7819–7822. ISSN 0002-7863. doi:10.1021/ja402393w.