1-金剛烷硫醇
| 1-金剛烷硫醇 | |
|---|---|
| |
| 識別 | |
| CAS號 | 34301-54-7 
|
| SMILES |
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| 性質 | |
| 化學式 | C10H16S |
| 摩爾質量 | 168.3 g·mol−1 |
| 外觀 | 白色固體[1] |
| 熔點 | 100-102 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
1-金剛烷硫醇是一種有機硫化合物，化學式為C10H15SH。它可由1-溴金剛烷、硫脲、氫溴酸和冰乙酸回流反應，再經氫氧化鈉水解、鹽酸酸化得到；[1]或由1-金剛烷醇和勞森試劑反應製得。[2]它可以被高錳酸鉀氧化為二(1-金剛烷基)二硫。[3]
參考文獻[編輯]
- ^ 1.0 1.1 1.2 Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer. Organic & Biomolecular Chemistry, 2015. doi:10.1039/C4OB02030H
- ^ S-alkyl Dithiocarbamates Synthesis through Electrochemical Multicomponent Reaction of Thiols, Hydrogen Sulfide, and Isocyanides. J. Org. Chem. 2023, 88, 17, 12311–12318. doi:10.1021/acs.joc.3c01017
- ^ Ground solid permanganate oxidative coupling of thiols into symmetrical/unsymmetrical disulfides: selective and improved process. Journal of Sulfur Chemistry, 2022. 43 (6). doi:10.1080/17415993.2022.2083914