一氯化銦

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一氯化銦
識別
CAS號 13465-10-6  checkY
性質
外觀 紅色或黃色
密度 4.218 g/cm3[1]
熔點 216 °C(489 K)
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

一氯化銦是一種無機化合物,化學式為InCl,它在120 °C以下為黃色的立方晶型,在此溫度之上為紅色的正交晶型。[2]它可由三氯化銦反應製得。[3][4]它和三氟甲磺酸在甲苯中反應,可以得到三氟甲磺酸銦(I)。[5]

參考文獻[編輯]

  1. ^ Van Den Berg, J. M. The crystal structure of the room temperature modification of indium chloride, InCl. Acta Crystallographica. 1966, 20 (6): 905–910. Bibcode:1966AcCry..20..905V. doi:10.1107/S0365110X66002032. 
  2. ^ Pardoe, Jennifer A. J.; Downs, Anthony J. Development of the Chemistry of Indium in Formal Oxidation States Lower than +3. Chemical Reviews. 2007-01-01, 107 (1): 2–45. ISSN 0009-2665. PMID 17212469. doi:10.1021/cr068027+ (英語). 
  3. ^ Annan, Theodore A.; Chadha, Raj K.; Doan, Peter; McConville, David H.; McGarvey, Bruce R.; Ozarowski, Andrzej; Tuck, Dennis G. One-electron transfer processes in the reaction of indium(I) halides with substituted o-quinones. Inorganic Chemistry. October 1990, 29 (20): 3936–3943. ISSN 0020-1669. doi:10.1021/ic00345a007 (英語). 
  4. ^ Poland, J. S.; Tuck, D. G. Coordination compounds of indium: XIV. The insertion of indium(I) iodide into carbon-iodide bonds. Journal of Organometallic Chemistry. 1972-09-01, 42 (2): 315–323. ISSN 0022-328X. doi:10.1016/S0022-328X(00)90080-9. 
  5. ^ Indium(i) trifluoromethanesulfonate and other soluble salts for univalent indium chemistry. Chem Commun. 2004. 250-251. doi:10.1039/B312983G.