馬拉普拉德反應
Malaprade反應（Malaprade reaction）是鄰二醇在溫和條件下被高碘酸或高碘酸鹽氧化得，產生醛或酮的二醇裂解反應。[1][2]這個反應是由Léon Malaprade首次報告的[3]。
用於糖化學中結構的鑑定。
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Malaprade反應 -
Malaprade反應機理
參見[編輯]
參考資料[編輯]
- ^ 406. Malaprade Reaction (Malaprade Oxidation). Comprehensive Organic Name Reactions and Reagents. Wiley. 2010: 1807–1810. doi:10.1002/9780470638859.conrr406.
- ^ H. O. House, Modern Synthetic Reactions (W. A. Benjamin, Menlo Park, California, 2nd ed., 1972) pp 353-359; K. W. Bentley in Elucidation of Organic Structures by Physical and Chemical Methods Pt. 2, K. W. Bentley, G. W. Kirby, Eds. (Wiley, New York, 2nd ed., 1973) pp 177-185.
- ^ L. Malaprade, Bull. Soc. Chim. Fr. [4] 43, 683 (1928); Compt. Rend. 186, 382 (1928).