氯化四氨合銅(II)

氯化四氨合銅(II)是一種配位化合物，化學式為[Cu(NH₃)₄]Cl₂。

製備及反應[編輯]

氯化四氨合銅(II)可由氯化銅和氨氣反應得到：^[1]

CuCl₂ + 4 NH₃ → [Cu(NH₃)₄]Cl₂

它也可以在氧化銅和氨-氯化銨的反應中得到：^[2]

CuO + 2 NH₃ + 2 NH₄Cl → [Cu(NH₃)₄]Cl₂ + H₂O

它和N-(吡啶-2-基)硫代苯甲醯胺在熱甲醇中反應，可以得到磚紅色的二[N-(吡啶-2-基)苯甲亞氨基]二硫化物的銅(I)羥基配合物。^[3]

^ K C Sharma, R P Sharma, J C Garg. Structural, electrical and optical properties of solution grown polycrystalline Cu 1-x Ag x Se thin films. Journal of Physics D: Applied Physics. 1992-06-14, 25 (6): 1019–1025 [2022-07-27]. ISSN 0022-3727. doi:10.1088/0022-3727/25/6/021. （原始內容存檔於2022-07-27）.
^ Peretrutov, A. A.; Chubenko, M. N. Solubility of zinc and copper oxides in ammonia solutions saturated with ammonium chloride. Estestvennye i Tekhnicheskie Nauki, 2008. 2: 59-61. ISSN 1684-2626.
^ Mw Fuller, V Costanzo, Ks Murray, Dsc Black, Tw Hambly, Mr Snow. Copper, Thioamide Complexes. Syntheses and Structures of Di-m-chloro-bis[N-(pyridin-2-yl)benzenecarbothioamide-S,N']dicopper(I) and of Bis[N-(pyridin-2-yl)benzenecarbothioamide-S,N']copper(I) Chloride, Complxes Containing Tetrahedrally Coordinated Copper Centres. Australian Journal of Chemistry. 1985, 38 (6): 865 [2022-07-27]. ISSN 0004-9425. doi:10.1071/CH9850865 （英語）.