苯甲醯溴

苯甲醯溴
識別
CAS號	618-32-6
性質
化學式	C6H5C(O)Br
莫耳質量	185.02 g·mol⁻¹
熔點	−24 °C（249 K）
沸點	218.5 °C（491.6 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

苯甲醯溴是一種有機化合物，化學式為C₇H₅BrO，它是苯甲酸的醯溴衍生物。它可由苯甲醛和二溴三聚氰酸在二氯甲烷中反應製得。^[2]苯甲醛和溴化亞碸^[3]或N-溴代丁二醯亞胺^[4]的反應，以及苯甲醯氟和三溴化硼的反應^[5]都可製得苯甲醯溴。它和苯硫酚亞鉈反應，可以得到硫代苯甲酸-S-苯酯；硒代底物的反應類似。^[6]在乙酸鈀催化下，它和苯基環氧乙烷反應，可以得到苯甲酸-β-溴苯乙酯。^[7]

參考文獻[編輯]

^ ^1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-09-21].
^ Young-Do Kwon, Minh Thanh La, Hee-Kwon Kim. Aerobic oxidative esterification and thioesterification of aldehydes using dibromoisocyanuric acid under mild conditions: no metal catalysts required. New Journal of Chemistry. 2018, 42 (13): 10833–10841 [2021-09-21]. ISSN 1144-0546. doi:10.1039/C8NJ01085D （英語）.
^ S. D. Saraf. Reaction of Thionyl Bromide with Aromatic Aldehydes. Journal für Praktische Chemie. 1981, 323 (4): 673–676 [2021-09-21]. ISSN 0021-8383. doi:10.1002/prac.19813230421. （原始內容存檔於2021-09-21）（德語）.
^ Yak-Fa Cheung. N-bromosuccinimide: direct oxidation of aldehydes to acid bromides. Tetrahedron Letters. 1979-01, 20 (40): 3809–3810 [2021-09-21]. doi:10.1016/S0040-4039(01)95530-3. （原始內容存檔於2018-06-10）（英語）.
^ Yagupol'skii, L. M.; Kondratenko, N. V. Exchange of halogen atoms in trihalomethyl groups. Zhurnal Obshchei Khimii, 1967. 37 (8): 1770-1775. ISSN 0044-460X.
^ Michael R. Detty, Gary P. Wood. Substitution reactions of thallous thiophenoxide and thallous phenyl selenide with halogen-bearing substrates. The Journal of Organic Chemistry. 1980-01, 45 (1): 80–89 [2021-09-21]. ISSN 0022-3263. doi:10.1021/jo01289a018 （英語）.
^ Jean Fotie, Brandy R. Adolph, Shreya V. Bhatt, Casey C. Grimm. Palladium(II) acetate catalyzed acylative cleavage of cyclic and acyclic ethers under neat conditions. Tetrahedron Letters. 2017-12, 58 (49): 4648–4651 [2021-09-21]. doi:10.1016/j.tetlet.2017.10.080. （原始內容存檔於2018-07-01）（英語）.

[SRC-1] 1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-09-21].

[2] Young-Do Kwon, Minh Thanh La, Hee-Kwon Kim. Aerobic oxidative esterification and thioesterification of aldehydes using dibromoisocyanuric acid under mild conditions: no metal catalysts required. New Journal of Chemistry. 2018, 42 (13): 10833–10841 [2021-09-21]. ISSN 1144-0546. doi:10.1039/C8NJ01085D （英語）.

[3] S. D. Saraf. Reaction of Thionyl Bromide with Aromatic Aldehydes. Journal für Praktische Chemie. 1981, 323 (4): 673–676 [2021-09-21]. ISSN 0021-8383. doi:10.1002/prac.19813230421. （原始內容存檔於2021-09-21）（德語）.

[4] Yak-Fa Cheung. N-bromosuccinimide: direct oxidation of aldehydes to acid bromides. Tetrahedron Letters. 1979-01, 20 (40): 3809–3810 [2021-09-21]. doi:10.1016/S0040-4039(01)95530-3. （原始內容存檔於2018-06-10）（英語）.

[5] Yagupol'skii, L. M.; Kondratenko, N. V. Exchange of halogen atoms in trihalomethyl groups. Zhurnal Obshchei Khimii, 1967. 37 (8): 1770-1775. ISSN 0044-460X.

[6] Michael R. Detty, Gary P. Wood. Substitution reactions of thallous thiophenoxide and thallous phenyl selenide with halogen-bearing substrates. The Journal of Organic Chemistry. 1980-01, 45 (1): 80–89 [2021-09-21]. ISSN 0022-3263. doi:10.1021/jo01289a018 （英語）.

[7] Jean Fotie, Brandy R. Adolph, Shreya V. Bhatt, Casey C. Grimm. Palladium(II) acetate catalyzed acylative cleavage of cyclic and acyclic ethers under neat conditions. Tetrahedron Letters. 2017-12, 58 (49): 4648–4651 [2021-09-21]. doi:10.1016/j.tetlet.2017.10.080. （原始內容存檔於2018-07-01）（英語）.

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