9-菲甲醛
| 9-菲甲醛 | |
|---|---|
| |
| 识别 | |
| CAS号 | 4707-71-5 
|
| 性质 | |
| 化学式 | C15H10O |
| 摩尔质量 | 206.24 g·mol−1 |
| 外观 | 浅黄色 |
| 熔点 | 101 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
9-菲甲醛是一种有机化合物，化学式为C15H10O。它可由9-菲甲醇的氧化[2]或9-锂基菲的甲酰化[3]制得。它和苯硼酸在催化下反应，可以得到(αS)-α-苯基-9-菲甲醇。[4]在乙酸钯催化下，它环己烷中加热，可以得到菲和一氧化碳。[5]
参考文献[编辑]
- ^ Symmetrical triad prototropic systems. Part IX. The influence of polynuclear aryl groups upon mobility and equilibrium in the αγ-diarylmethyleneazomethine system. J. Chem. Soc., 1933, 37-45. doi:10.1039/JR9330000037.
- ^ Bis(2,2'-bipyridyl)copper(II) permanganate (BBCP): A mild and versatile oxidant in organic synthesis. Tetrahedron (1984), 40(23), 5001-5004. doi:10.1016/S0040-4020(01)91340-7.
- ^ Bifunctional antitumor agents. Derivatives of pyrrolo[9, 10-b]phenanthrene—A DNA intercalative delivery template. Tetrahedron (1997), 53(43), 14599-14614. doi:10.1016/S0040-4020(97)00991-5.
- ^ Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis. ACS Catalysis (2019), 9(2), 1457-1463. doi:10.1021/acscatal.8b04787.
- ^ A general and efficient aldehyde decarbonylation reaction by using a palladium catalyst. Chemical Communications (Cambridge, United Kingdom) (2012), 48(35), 4253-4255. doi:10.1039/C2CC31144E.