9-菲甲醛
| 9-菲甲醛 | |
|---|---|
| |
| 識別 | |
| CAS號 | 4707-71-5 
|
| 性質 | |
| 化學式 | C15H10O |
| 摩爾質量 | 206.24 g·mol−1 |
| 外觀 | 淺黃色 |
| 熔點 | 101 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
9-菲甲醛是一種有機化合物，化學式為C15H10O。它可由9-菲甲醇的氧化[2]或9-鋰基菲的甲酰化[3]製得。它和苯硼酸在催化下反應，可以得到(αS)-α-苯基-9-菲甲醇。[4]在乙酸鈀催化下，它環己烷中加熱，可以得到菲和一氧化碳。[5]
參考文獻[編輯]
- ^ Symmetrical triad prototropic systems. Part IX. The influence of polynuclear aryl groups upon mobility and equilibrium in the αγ-diarylmethyleneazomethine system. J. Chem. Soc., 1933, 37-45. doi:10.1039/JR9330000037.
- ^ Bis(2,2'-bipyridyl)copper(II) permanganate (BBCP): A mild and versatile oxidant in organic synthesis. Tetrahedron (1984), 40(23), 5001-5004. doi:10.1016/S0040-4020(01)91340-7.
- ^ Bifunctional antitumor agents. Derivatives of pyrrolo[9, 10-b]phenanthrene—A DNA intercalative delivery template. Tetrahedron (1997), 53(43), 14599-14614. doi:10.1016/S0040-4020(97)00991-5.
- ^ Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis. ACS Catalysis (2019), 9(2), 1457-1463. doi:10.1021/acscatal.8b04787.
- ^ A general and efficient aldehyde decarbonylation reaction by using a palladium catalyst. Chemical Communications (Cambridge, United Kingdom) (2012), 48(35), 4253-4255. doi:10.1039/C2CC31144E.